Phenazie

Base Information

  • PRODUCT:Phenazie
  • CAS.:92-82-0
  • MF:C12H8N2
  • Molecular Weight:180.209
  • Purity:99%

Product Details

CAS： 92-82-0

MF： C12H8N2

Appearance： yellow to brown crystalline powder

Quality Factory Supply Phenazie 92-82-0 Offer with Efficient Transportation

  • Molecular Formula:C12H8N2
  • Molecular Weight:180.209
  • Appearance/Colour:yellow to brown crystalline powder 
  • Melting Point:172-176 °C(lit.) 
  • Refractive Index:1.5200 (estimate) 
  • Boiling Point:357.2 °C at 760 mmHg 
  • PKA:1.20(at 20℃) 
  • Flash Point:160.3 °C 
  • PSA：25.78000 
  • Density:1.25 g/cm3 
  • LogP:2.78300 

Phenazine(Cas 92-82-0) Usage

Chemical Properties

YELLOW TO BROWN CRYSTALLINE POWDER

Uses

Phenazine (cas# 92-82-0) is a compound useful in organic synthesis.

Definition

ChEBI: An azaarene that is anthracene in which the carbon atoms at positions 9 and 10 are replaced by nitrogen atoms.

Safety Profile

Poison by intraperitoneal and intravenous routes. Questionable carcinogen with experimental tumorigenic data. When heated to decomposition it emits toxic fumes of NOx.

Purification Methods

Phenazine crystallises from EtOH, CHCl3 or ethyl acetate, after pre-treatment with activated charcoal. It can be sublimed in vacuo and purified by zone refining. [Beilstein 23/8 V 389.]

InChI:InChI=1/C12H8N2/c1-2-6-10-9(5-1)13-11-7-3-4-8-12(11)14-10/h1-8H

92-82-0 Relevant articles

Enthalpies of combustion of phenazine N-oxide, phenazine, benzofuroxan, and benzofurazan: the dissociation enthalpies of the (N-O) bonds

Leitao, M. Luisa P.,Pilcher, G.,Acree, W. E.,Zvaigzne, Anita I.,Tucker, Sheryl A.,et al.

, p. 923 - 928 (1990)

The standard (p0 = 0.1 MPa) molar enthal...

Solvent Dependent Bergman Cyclization of 2,3-Diethynylquinoxaline

Kim, Chang-Sik,Russell, K. C.

, p. 3835 - 3838 (1999)

Kinetics of thermocyclization of 2,3-die...

Enhanced catalytic activity in organic solvents using molecularly dispersed haemoglobin-polymer surfactant constructs

Zhang, Yixiong,Patil, Avinash J.,Perriman, Adam W.,Mann, Stephen

, p. 9561 - 9563 (2013)

The surface of haemoglobin (Hb) is chemi...

-

Chacko et al.

, p. 321 (1979)

-

One-pot production of phenazine from lignin-derived catechol

He, Zhimin,Qi, Wei,Ren, Tianyu,Yan, Ning

, p. 1224 - 1230 (2022/02/17)

Upgrading lignin-derived monomeric produ...

The silver-mediated annulation of arylcarbamic acids and nitrosoarenes toward phenazines

Chen, Fan,Cheng, Jiang,Qian, Peng-Cheng,Wang, Lu

, (2021/12/17)

A silver-mediated annulation between ary...

An umpolung strategy for rapid access to thermally activated delayed fluorescence (TADF) materials based on phenazine

Cheng, Hu,Guo, Qiang,Lan, Jingbo,Ran, Chunhao,Wu, Di,Zhang, Huaxing

supporting information, p. 1581 - 1584 (2022/02/10)

Herein, Ag(I)-promoted regioselective in...

Decarboxylation of Aromatic Carboxylic Acids by the Prenylated-FMN-dependent Enzyme Phenazine-1-carboxylic Acid Decarboxylase

Datar, Prathamesh M.,Marsh, E. Neil G.

, p. 11723 - 11732 (2021/09/28)

Phenazine-1-carboxylic acid decarboxylas...

92-82-0 Process route

N-butylamine
109-73-9,85404-21-3

N-butylamine

5,10-Dihydrophenazin-5,10-dicarbonsaeure-diphenylester
158670-54-3

5,10-Dihydrophenazin-5,10-dicarbonsaeure-diphenylester

Phenazin
92-82-0

Phenazin

N,N'-di-n-butylurea
1792-17-2

N,N'-di-n-butylurea

N,N'-Dibutyl-5,10-dihydrophenazin-5,10-dicarboxamid

N,N'-Dibutyl-5,10-dihydrophenazin-5,10-dicarboxamid

Conditions
Conditions Yield
5,10-Dihydrophenazin-5,10-dicarbonsaeure-diphenylester
158670-54-3

5,10-Dihydrophenazin-5,10-dicarbonsaeure-diphenylester

Phenazin
92-82-0

Phenazin

N,N'-di-n-butylurea
1792-17-2

N,N'-di-n-butylurea

N,N'-Dibutyl-5,10-dihydrophenazin-5,10-dicarboxamid

N,N'-Dibutyl-5,10-dihydrophenazin-5,10-dicarboxamid

Conditions
Conditions Yield
With N-butylamine;

92-82-0 Upstream products

  • 4829-73-6
    4829-73-6

    1,2,3,4-tetrahydrophenazine

  • 613-32-1
    613-32-1

    5,10-dihydrophenazine

  • 64-17-5
    64-17-5

    ethanol

  • 655-86-7
    655-86-7

    2,3-diaminephenazine

92-82-0 Downstream products

  • 62248-06-0
    62248-06-0

    5,10-dibenzyl-5,10-dihydrophenazine

  • 10510-77-7
    10510-77-7

    N-ethyldibenzopyrazine ethyl sulfate salt

  • 4733-23-7
    4733-23-7

    phenazine; compound with 5,10-dihydro-phenazine

  • 4733-23-7
    4733-23-7

    phenazine; compound with 5,10-dihydro-phenazine

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